Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/5859
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dc.contributor.authorAdukpo, Genevieve Etornam-
dc.contributor.authorBorrmann, Tobias-
dc.contributor.authorManski, René-
dc.contributor.authorDíaz, Rosa I. Sáez-
dc.contributor.authorStohrer, Wolf-Dieter-
dc.contributor.authorMontforts, Franz-Peter-
dc.date.accessioned2021-08-16T09:43:20Z-
dc.date.available2021-08-16T09:43:20Z-
dc.date.issued2007-
dc.identifier.issn23105496-
dc.identifier.urihttp://hdl.handle.net/123456789/5859-
dc.description9p:, ill.en_US
dc.description.abstractThe enantiomerically pure pyrrolidine diester 4 is a useful building block for the synthesis of chiral hydroporphyrin compounds. Treatment of optically active aromatic amines with bislactone 5 gave pairs of N-alkylated lactam-lactone diastereomers 6 and 8. These diastereomers were separated by MPL chromatography and in the case of 8 they could be debenzylated to yield the enantiomerically pure lactam-lactone 7 and its enantiomer. The (–)-lactam-lactone enantiomer 7 was further transformed into building block 4en_US
dc.language.isoenen_US
dc.publisherUniversity of Cape Coasten_US
dc.subjectHydroporphyrinsen_US
dc.subjectNitrogen heterocyclesen_US
dc.subjectChiral resolutionen_US
dc.subjectCircular dichroismen_US
dc.titleSynthesis of an enantiomerically pure building block for the synthesis of hydroporphyrinsen_US
dc.typeArticleen_US
Appears in Collections:Department of Chemistry

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